this handle was colored with Permanganate By Me, it was a very light White Tail Antler
also I matched The edges of this M / Ivory with the bark of the ivory on this one.
this one I finished 9/27/2005
© 2004
.
Mix a little water with potasium permanganate crystals (from drug store) and paint on untill desired depth of color. Don't freak out when it goes purple, it will go brown. Wash of excess, seal with wax or mineral oil. I use sandlewood oil,
love the smell. by Peter Del Raso
Synonyms: Permanganic acid, potassium salt;
Condy's crystals
CAS No.: 7722-64-7
Molecular Weight: 158.03
Chemical Formula: KMnO4
Product Codes: J.T. Baker: 3227, 3228, 3232 Mallinckrodt: 7056, 7068
Ingredient CAS No Percent Hazardous
--------------------------------------- ------------ ------- ---------
Potassium Permanganate 7722-64-7 90 - 100% Yes
Emergency Overview
--------------------------
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
CORROSIVE. CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR
INHALED.
J.T. Baker SAF-T-DATA(tm) Ratings (Provided here for your
convenience)
-----------------------------------------------------------------------------------------------------------
Health Rating: 2 - Moderate
Flammability Rating: 0 - None
Reactivity Rating: 3 - Severe (Oxidizer)
Contact Rating: 2 - Moderate
Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES
Storage Color Code: Yellow (Reactive)
-----------------------------------------------------------------------------------------------------------
Potential Health Effects
----------------------------------
Inhalation:
Causes irritation to the respiratory tract. Symptoms may include coughing,
shortness of breath. High concentrations can cause pulmonary edema.
Ingestion:
Ingestion of solid or high concentrations causes severe distress of
gastro-intestinal system with possible burns and edema; slow pulse; shock with
fall of blood pressure. May be fatal. Ingestion of concentrations up to 1%
causes burning of the throat, nausea, vomiting, and abdominal pain; 2-3% causes
anemia and swelling of the throat with possible suffocation; 4-5% may cause
kidney damage.
Skin Contact:
Dry crystals and concentrated solutions are caustic causing redness, pain,
severe burns, brown stains in the contact area and possible hardening of outer
skin layer. Diluted solutions are only mildly irritating to the skin.
Eye Contact:
Eye contact with crystals (dusts) and concentrated solutions causes severe
irritation, redness, blurred vision and can cause severe damage, possibly
permanent.
Chronic Exposure:
Prolonged skin contact may cause irritation, defatting, and dermatitis. Chronic
manganese poisoning can result from excessive inhalation exposure to manganese
dust and involves impairment of the central nervous system. Early symptoms
include sluggishness, sleepiness, and weakness in the legs. Advanced cases have
shown symptoms of fixed facial expression, emotional disturbances, spastic
gait, and falling.
Aggravation of Pre-existing Conditions:
No information found.
Inhalation:
Remove to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical attention immediately.
Ingestion:
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never
give anything by mouth to an unconscious person. Get medical attention
immediately.
Skin Contact:
Immediately flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical attention immediately.
Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact:
Immediately flush eyes with plenty of water for at least 15 minutes, lifting
lower and upper eyelids occasionally. Get medical attention immediately.
Fire:
Not combustible, but substance is a strong oxidizer and its heat of reaction
with reducing agents or combustibles may cause ignition. Contact with
oxidizable substances may cause extremely violent combustion.
Explosion:
Strong oxidants may explode when shocked, or if exposed to heat, flame, or
friction. Also may act as initiation source for dust or vapor explosions.
Contact with oxidizable substances may cause extremely violent combustion.
Sealed containers may rupture when heated. Sensitive to mechanical impact.
Fire Extinguishing Media:
Use water spray to blanket fire, cool fire exposed containers, and to flush
non-ignited spills or vapors away from fire. Suffocating type extinguishers are
not as effective as water. Do not allow water runoff to enter sewers or
waterways.
Special Information:
In the event of a fire, wear full protective clothing and NIOSH-approved
self-contained breathing apparatus with full facepiece operated in the pressure
demand or other positive pressure mode.
Remove all sources of ignition. Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Clean up spills in a manner that does not disperse dust into the air. Use non-sparking tools and equipment. Reduce airborne dust and prevent scattering by moistening with water. Pick up spill for recovery or disposal and place in a closed container. US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-8802.
Keep in a tightly closed container, stored in a cool, dry, ventilated area. Protect against physical damage and moisture. Isolate from any source of heat or ignition. Avoid storage on wood floors. Separate from incompatibles, combustibles, organic or other readily oxidizable materials. Containers of this material may be hazardous when empty since they retain product residues (dust, solids); observe all warnings and precautions listed for the product.
Airborne Exposure Limits:
- OSHA Permissible Exposure Limit (PEL): 5 mg/m3 Ceiling for manganese
compounds as Mn - ACGIH Threshold Limit Value (TLV): 0.2 mg/m3 (TWA) for
manganese, elemental and inorganic compounds as Mn
Ventilation System:
A system of local and/or general exhaust is recommended to keep employee
exposures below the Airborne Exposure Limits. Local exhaust ventilation is
generally preferred because it can control the emissions of the contaminant at
its source, preventing dispersion of it into the general work area. Please
refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended
Practices, most recent edition, for details.
Personal Respirators (NIOSH Approved):
If the exposure limit is exceeded, a half-face dust/mist respirator may be worn
for up to ten times the exposure limit or the maximum use concentration
specified by the appropriate regulatory agency or respirator supplier,
whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50
times the exposure limit, or the maximum use concentration specified by the
appropriate regulatory agency, or respirator supplier, whichever is lowest. For
emergencies or instances where the exposure levels are not known, use a
full-facepiece positive-pressure, air-supplied respirator. WARNING:
Air-purifying respirators do not protect workers in oxygen-deficient
atmospheres.
Skin Protection:
Wear impervious protective clothing, including boots, gloves, lab coat, apron
or coveralls, as appropriate, to prevent skin contact.
Eye Protection:
Use chemical safety goggles and/or full face shield where dusting or splashing
of solutions is possible. Maintain eye wash fountain and quick-drench
facilities in work area.
Appearance:
Purple-bronze crystals.
Odor:
Odorless.
Solubility:
7 g in 100 g of water.
Density:
2.7
pH:
No information found.
% Volatiles by volume @ 21C (70F):
0
Boiling Point:
Not applicable.
Melting Point:
ca. 240C (ca. 464F)
Vapor Density (Air=1):
5.40
Vapor Pressure (mm Hg):
No information found.
Evaporation Rate (BuAc=1):
No information found.
Stability:
Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products:
Toxic metal fumes may form when heated to decomposition.
Hazardous Polymerization:
Will not occur.
Incompatibilities:
Powdered metals, alcohol, arsenites, bromides, iodides, phosphorous, sulfuric
acid, organic compounds, sulfur, activated carbon, hydrides, strong hydrogen
peroxide, ferrous or mercurous salts, hypophosphites, hyposulfites, sulfites,
peroxides, and oxalates.
Conditions to Avoid:
Heat, flames, ignition sources and incompatibles.
Investigated as a mutagen, reproductive effector. Oral rat LD50: 1090 mg/kg.
--------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen---Ingredient Known Anticipated IARC Category
------------------------------------ ----- ----------- -------------
Potassium Permanganate (7722-64-7) No No None
Environmental Fate:
No information found.
Environmental Toxicity:
This material may be toxic to aquatic life.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
Domestic (Land, D.O.T.)
-----------------------
Proper Shipping Name: RQ, POTASSIUM PERMANGANATE
Hazard Class: 5.1
UN/NA: UN1490
Packing Group: II
Information reported for product/size: 110LB
International (Water, I.M.O.)
-----------------------------
Proper Shipping Name: POTASSIUM PERMANGANATE
Hazard Class: 5.1
UN/NA: UN1490
Packing Group: II
Information reported for product/size: 110LB
International (Air, I.C.A.O.)
-----------------------------
Proper Shipping Name: POTASSIUM PERMANGANATE
Hazard Class: 5.1
UN/NA: UN1490
Packing Group: II
Information reported for product/size: 110LB
--------\Chemical Inventory Status - Part 1\---------------------------------Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Potassium Permanganate (7722-64-7) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\--------------------------------- --Canada--Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Potassium Permanganate (7722-64-7) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\-----------------SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Potassium Permanganate (7722-64-7) No No No Manganese co
--------\Federal, State & International Regulations - Part 2\-----------------RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Potassium Permanganate (7722-64-7) 100 No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes
SARA 311/312: Acute: Yes Chronic: Yes Fire: Yes Pressure: No
Reactivity: No (Pure / Solid)
Australian Hazchem Code: 2Y
Poison Schedule: S6
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled
Products Regulations (CPR) and the MSDS contains all of the information
required by the CPR.
NFPA Ratings: Health: 1 Flammability:
0 Reactivity: 0 Other: Oxidizer
Label Hazard Warning:
DANGER! STRONG OXIDIZER. CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE. CORROSIVE.
CAUSES BURNS TO ANY AREA OF CONTACT. HARMFUL IF SWALLOWED OR INHALED.
Label Precautions:
Keep from contact with clothing and other combustible materials. Store in a
tightly closed container. Do not store near combustible materials. Remove and
wash contaminated clothing promptly. Do not get in eyes, on skin, or on
clothing. Do not breathe dust. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling.
Label First Aid:
In case of contact, immediately flush eyes or skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. If swallowed, DO NOT
INDUCE VOMITING. Give large quantities of water. Never give anything by mouth
to an unconscious person. In all cases get medical attention immediately.
Product Use:
Laboratory Reagent.
Revision Information:
Pure. New 16 section MSDS format, all sections have been revised.
Disclaimer:
************************************************************************************************
Mallinckrodt Baker, Inc. provides the information contained herein in good
faith but makes no representation as to its comprehensiveness or accuracy. This
document is intended only as a guide to the appropriate precautionary handling
of the material by a properly trained person using this product. Individuals
receiving the information must exercise their independent judgment in
determining its appropriateness for a particular purpose. MALLINCKRODT BAKER,
INC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED,
INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE
PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, MALLINCKRODT BAKER, INC.
WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS
INFORMATION.
************************************************************************************************
Prepared by: Strategic Services Division
Phone Number: (314) 539-1600 (U.S.A.)
**********************************
this handle was colored with Permanganate By Me, it was a very light White Tail Antler
also I matched The edges of this M / Ivory with the bark of the ivory on this one.
this one I finished 9/27/2005
© 2004
.